Try this if you mean you have cloned flutter to /opt folder
export PATH="$PATH:/opt/flutter/bin"
Also if you doesn't mean that and you solely mean ~/opt folder then first verify your flutter installation by typing
~/opt/flutter/bin/flutter
in your terminal,
It should launch flutter it your terminal if not then either your installation is broken or you have to type
chmod +x -R ~/opt/flutter/bin
to make flutter executable if it's not.
PS: Also don't forget to restart your shell if you haven't cause you have to restart you shell after changing something in your .rc files.
I hope I have helped you if not please comment so that I can improve the answer.
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